000 -LEADER |
fixed length control field |
a |
003 - CONTROL NUMBER IDENTIFIER |
control field |
OSt |
005 - DATE AND TIME OF LATEST TRANSACTION |
control field |
20220201150529.0 |
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION |
fixed length control field |
220201b xxu||||| |||| 00| 0 eng d |
040 ## - CATALOGING SOURCE |
Original cataloging agency |
AIKTC-KRRC |
Transcribing agency |
AIKTC-KRRC |
100 ## - MAIN ENTRY--PERSONAL NAME |
9 (RLIN) |
11679 |
Author |
Utsukihara, Takamitsu |
245 ## - TITLE STATEMENT |
Title |
Production of chiral aromatic alcohol by acetophenone and 1-arylethanol derivatives using vegetables |
250 ## - EDITION STATEMENT |
Volume, Issue number |
Vol.58(B), Jan. |
260 ## - PUBLICATION, DISTRIBUTION, ETC. |
Place of publication, distribution, etc. |
New Delhi |
Name of publisher, distributor, etc. |
CSIR |
Year |
2019 |
300 ## - PHYSICAL DESCRIPTION |
Pagination |
69-74p. |
520 ## - SUMMARY, ETC. |
Summary, etc. |
We have studied the biotransformation of acetophenone derivatives (1a-1f) and 1-arylethanol derivatives (2a-2e, 2g, 2h) using various vegetables. It is found that the reduction of acetophenone derivatives (1a-1f) using carrot (Ducus carota) gives (S)-1-arylethanols with high enantioselectivity. On the other hand, biooxidation of 1-arylethanols (2a-2e, 2g, 2h) using potato (Solanum tuberosum) is oxidized to give (R)-1-arylethanols as major product with high stereoselectivity. Carrot (D. carota) is the best catalyst for this reduction and shows a good reaction yield and enatioselectivity. On the other hand, it is found that the racemic alcohols are converted into the corresponding (R)-alcohols with high ee using Japanese potato (S. tuberosum) as catalyst. The availability of the enzymatic system using various vegetables is convenient and an eco-friendly system. |
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM |
9 (RLIN) |
5009 |
Topical term or geographic name entry element |
GENERAL CHEMISTRY |
700 ## - ADDED ENTRY--PERSONAL NAME |
9 (RLIN) |
11877 |
Co-Author |
Horiuchi, C. Akira |
773 0# - HOST ITEM ENTRY |
Place, publisher, and date of publication |
New Delhi NISCAIR-CSIR 2005 |
Title |
Indian journal of chemistry (Section B) |
856 ## - ELECTRONIC LOCATION AND ACCESS |
URL |
http://nopr.niscair.res.in/bitstream/123456789/45707/1/IJCB%2058B%281%29%2069-74.pdf |
Link text |
Click here |
942 ## - ADDED ENTRY ELEMENTS (KOHA) |
Source of classification or shelving scheme |
|
Koha item type |
Articles Abstract Database |