Dielectric characterization and molecular interaction behaviour in binary mixtures of methyl acetate with 1-butanol and 1-pentanol (Record no. 16732)

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control field OSt
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control field 20220617155753.0
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fixed length control field 220617b xxu||||| |||| 00| 0 eng d
040 ## - CATALOGING SOURCE
Original cataloging agency AIKTC-KRRC
Transcribing agency AIKTC-KRRC
100 ## - MAIN ENTRY--PERSONAL NAME
9 (RLIN) 16644
Author Kolhe, S. B.
245 ## - TITLE STATEMENT
Title Dielectric characterization and molecular interaction behaviour in binary mixtures of methyl acetate with 1-butanol and 1-pentanol
250 ## - EDITION STATEMENT
Volume, Issue number Vol.57(12), Dec
260 ## - PUBLICATION, DISTRIBUTION, ETC.
Place of publication, distribution, etc. New Delhi
Name of publisher, distributor, etc. CSIR
Year 2019
300 ## - PHYSICAL DESCRIPTION
Pagination 900-910p.
520 ## - SUMMARY, ETC.
Summary, etc. The dielectric constant (ɛs) and relaxation time () of binary mixtures of methyl acetate with alcohols (1-butanol and 1-pentanol) have been investigated at fifteen molar concentrations over the entire mixing range at 288 K, 298 K, 308 K and 318 K using time domain reflectometery technique over the frequency range from 10 MHz to 10 GHz. The relaxation in these mixtures can be described by a single relaxation time using the Debye model. The concentration dependent plots of excess dielectric constant (ɛE), excess inverse relaxation time (1/)E, Kirkwood correlation factor (geff), thermodynamic parameters such as enthalpy of activation (H) and Gibbs free energy (G) of activation and Bruggman factor (fB) have been used to explore the complexes formed between unlike molecules, dipolar ordering, hydrogen bond molecular connectivity’s and their strength in the binary mixtures. Results confirm that there are strong hydrogen-bond interactions between unlike molecules of ester-alcohol mixtures.
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
9 (RLIN) 4642
Topical term or geographic name entry element Humanities and Applied Science
700 ## - ADDED ENTRY--PERSONAL NAME
9 (RLIN) 16645
Co-Author Undre, P. B.
773 0# - HOST ITEM ENTRY
Title Indian journal of pure & applied physics (IJPAP)
International Standard Serial Number 0019-5596
Place, publisher, and date of publication New Delhi CSIR-NISCAIR
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URL http://nopr.niscpr.res.in/bitstream/123456789/52773/1/IJPAP%2057%2812%29%20900-910.pdf
Link text Click here
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Koha item type Articles Abstract Database
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          School of Engineering & Technology School of Engineering & Technology Archieval Section 2022-06-17 2022-0811 2022-06-17 2022-06-17 Articles Abstract Database
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