Solvent effects on the dipole moments and photo physical properties of laser dye (Record no. 8064)

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fixed length control field a
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control field OSt
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20220721154818.0
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 190101b xxu||||| |||| 00| 0 eng d
040 ## - CATALOGING SOURCE
Original cataloging agency AIKTC-KRRC
Transcribing agency AIKTC-KRRC
100 ## - MAIN ENTRY--PERSONAL NAME
9 (RLIN) 7337
Author Melavanki, R M
245 ## - TITLE STATEMENT
Title Solvent effects on the dipole moments and photo physical properties of laser dye
250 ## - EDITION STATEMENT
Volume, Issue number Vol. 56(10), October
260 ## - PUBLICATION, DISTRIBUTION, ETC.
Place of publication, distribution, etc. New Delhi
Year 2018
Name of publisher, distributor, etc. CSIR
300 ## - PHYSICAL DESCRIPTION
Pagination 749-754
520 ## - SUMMARY, ETC.
Summary, etc. The absorption and emission spectra of fluorescent laser dye namely, 4,4”’-bis-2-butyyloctyl-oxy)-P-quaterphenyl have been recorded at room temperature in solvents of different polarities. The exited state dipole moments (µe) have been estimated from Lippert’s, Bakhshiev’s and Kawski-Chamma-Viallet’s equations using the variation of Stoke’s shift with the solvent dielectric constant and refractive index. The geometry of the molecule has been fully optimized and the µg has also been calculated theoretically by Gaussian 03 software using B3LYP/6-31g* level of theory. The µg and µe have been calculated by means of solvatochromic shift method. It has been observed that µe is higher than µg, indicating a substantial redistribution of the π-electron densities in a more polar excited state for the selected laser dye. Further, the changes in the dipole moment (µ) has been calculated both from solvatochromic shift method and microscopic empirical solvent polarity parameter (E) and values are compared.
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
9 (RLIN) 4642
Topical term or geographic name entry element Humanities and Applied Sciences
700 ## - ADDED ENTRY--PERSONAL NAME
9 (RLIN) 7338
Co-Author Muttannavar, V. T.
773 0# - HOST ITEM ENTRY
Place, publisher, and date of publication New Delhi CSIR-NISCAIR
Title Indian journal of pure & applied physics (IJPAP)
International Standard Serial Number 0019-5596
856 ## - ELECTRONIC LOCATION AND ACCESS
Link text Click here
URL http://nopr.niscair.res.in/handle/123456789/45250
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Source of classification or shelving scheme
Koha item type Articles Abstract Database
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          School of Engineering & Technology School of Engineering & Technology Archieval Section 2019-03-29 2018151 2019-06-10 2019-03-29 Articles Abstract Database
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