Activation parameters of conjugated polyaniline electrolyte via dielectric relaxation technique (Record no. 8077)

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fixed length control field a
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control field OSt
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20220721154821.0
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fixed length control field 190101b xxu||||| |||| 00| 0 eng d
040 ## - CATALOGING SOURCE
Original cataloging agency AIKTC-KRRC
Transcribing agency AIKTC-KRRC
100 ## - MAIN ENTRY--PERSONAL NAME
9 (RLIN) 7360
Author Amaechi, Ifeanyichukwu C.
245 ## - TITLE STATEMENT
Title Activation parameters of conjugated polyaniline electrolyte via dielectric relaxation technique
250 ## - EDITION STATEMENT
Volume, Issue number Vol. 56(10), October
260 ## - PUBLICATION, DISTRIBUTION, ETC.
Place of publication, distribution, etc. New Delhi
Year 2018
Name of publisher, distributor, etc. CSIR
300 ## - PHYSICAL DESCRIPTION
Pagination 830-836
520 ## - SUMMARY, ETC.
Summary, etc. The synthesis and relaxation mechanism of polyaniline electrolyte in form of thin film by oxidative polymerization in the presence of inorganic acid have been reported. The films have been characterized by scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, 2-point probe and UV-Vis absorption spectroscopy. The mechanism of electrical conductivity for the disordered system has been explained in terms of Mott’s variable-range hopping for the intrinsic conduction of the protonated long chain. The dielectric parameters including real part, imaginary part and loss tangent have been measured between the wavelength range 400 – 1100 nm. These have been employed in the determination of dielectric relaxation time τ which exhibits Arrhenius-like behaviour. Finally, the temperature dependent relaxation time which is a function of activation energy of dipole orientation otherwise known as Gibbs free energy ∆G#, has been utilized in estimation of some thermodynamic parameters such as enthalpy ∆H# and entropy ∆S#. The SEM shows an aggregation of randomly oriented fibrous network of polyaniline on the surface of substrate. Fourier transform infrared confirms the acoustic vibrational modes of the long chain polymer.
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
9 (RLIN) 4642
Topical term or geographic name entry element Humanities and Applied Sciences
700 ## - ADDED ENTRY--PERSONAL NAME
9 (RLIN) 7361
Co-Author Balogun, Bashiru B.
700 ## - ADDED ENTRY--PERSONAL NAME
9 (RLIN) 7363
Co-Author Nwachukwu, Michael I.
773 0# - HOST ITEM ENTRY
Title Indian journal of pure & applied physics (IJPAP)
Place, publisher, and date of publication New Delhi CSIR-NISCAIR
International Standard Serial Number 0019-5596
856 ## - ELECTRONIC LOCATION AND ACCESS
Link text Click here
URL http://nopr.niscair.res.in/handle/123456789/45241
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Source of classification or shelving scheme
Koha item type Articles Abstract Database
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          School of Engineering & Technology School of Engineering & Technology Archieval Section 2019-03-29 2018160 2019-06-10 2019-03-29 Articles Abstract Database
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