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Visible light-mediated amidation of aryl diazonium salts with nitriles – A novel photo-Ritter type reaction

By: Singh, Anil K.
Contributor(s): Yadav, Vinod K.
Publisher: New Delhi CSIR 2021Edition: Vol.58(B), Feb.Description: 140-146p.Subject(s): GENERAL CHEMISTRYOnline resources: Click here In: Indian journal of chemistry (Section B)Summary: An efficient, metal-free protocol for amidation of aryl diazonium salts with nitriles has been developed utilizing visible light as an inexpensive, safer and sustainable energy source and eosin Y as an organophotoredox catalyst. The reaction follows a free radical pathway and offers an environmentally sustainable approach to a variety of amides in a simple one-pot procedure at room temperature.
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An efficient, metal-free protocol for amidation of aryl diazonium salts with nitriles has been developed utilizing visible light as an inexpensive, safer and sustainable energy source and eosin Y as an organophotoredox catalyst. The reaction follows a free radical pathway and offers an environmentally sustainable approach to a variety of amides in a simple one-pot procedure at room temperature.

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