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Enantiospecific syntheses of oxacyclodecanes from carvone via mild Lewis acid mediated etherifcation

By: Adusumilli, Srikrishna.
Contributor(s): Satyanarayana, Gedu.
Publisher: New Delhi CSIR 2019Edition: Vol.58(B), March.Description: 353-361p.Subject(s): GENERAL CHEMISTRYOnline resources: Click here In: Indian journal of chemistry (Section B)Summary: An efficient enantiospecific syntheses of oxatri-/tetra-cyclodecanes have been accomplished starting from (R)-carvone. A mild Lewis acid (BF3×OEt2) mediated intramolecular etherification is used as the key step. Structurally aesthetic tri- and tetracyclic ethers have been synthesized.
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An efficient enantiospecific syntheses of oxatri-/tetra-cyclodecanes have been accomplished starting from (R)-carvone. A mild Lewis acid (BF3×OEt2) mediated intramolecular etherification is used as the key step. Structurally aesthetic tri- and tetracyclic ethers have been synthesized.

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