Effect of solvent change on chemical shifts of 4-benzyl-4-hydroxypiperidines
By: Maruthavanan, T
.
Contributor(s): Manimekalai, A.
Publisher: New Delhi CSIR 2022Edition: Vol.61, Nov.Description: 1180-1183p.Subject(s): GENERAL CHEMISTRYOnline resources: Click here
In:
Indian journal of chemistry (Section B)Summary: 4-Benzyl-4-hydroxypiperidines 1-8 have been synthesized through Mannich reaction and were characterized through
high resolution 1H and 13C NMR spectra in CDCl 3.The conformational studies of the above eight compounds have been
thoroughly done by using proton and 13C spectral data and the assigned conformations were also supported by Hybrid
HF/DFT B3LYP/6-3G* calculations. These results are published earlier by us. In order to study the effect of solvent on the
chemical shifts of these piperidines, 1H NMR spectra were recorded in C6D6 and DMSO-d6. The effect of change of solvents
results appreciable change in the chemical shifts of various protons in the title compounds.
| Item type | Current location | Call number | Status | Date due | Barcode | Item holds |
|---|---|---|---|---|---|---|
Articles Abstract Database
|
School of Pharmacy Archieval Section | Not for loan | 2023-0639 |
4-Benzyl-4-hydroxypiperidines 1-8 have been synthesized through Mannich reaction and were characterized through
high resolution 1H and 13C NMR spectra in CDCl 3.The conformational studies of the above eight compounds have been
thoroughly done by using proton and 13C spectral data and the assigned conformations were also supported by Hybrid
HF/DFT B3LYP/6-3G* calculations. These results are published earlier by us. In order to study the effect of solvent on the
chemical shifts of these piperidines, 1H NMR spectra were recorded in C6D6 and DMSO-d6. The effect of change of solvents
results appreciable change in the chemical shifts of various protons in the title compounds.
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