Maruthavanan, T. <br/><br/>
Effect of solvent change on chemical shifts of 4-benzyl-4-hydroxypiperidines 

 - Vol.61, Nov 
 - New Delhi  CSIR  2022 
 - 1180-1183p. 
<br/><br/> 4-Benzyl-4-hydroxypiperidines 1-8 have been synthesized through Mannich reaction and were characterized through<br/>high resolution 1H and 13C NMR spectra in CDCl 3.The conformational studies of the above eight compounds have been<br/>thoroughly done by using proton and 13C spectral data and the assigned conformations were also supported by Hybrid<br/>HF/DFT B3LYP/6-3G* calculations. These results are published earlier by us. In order to study the effect of solvent on the<br/>chemical shifts of these piperidines, 1H NMR spectra were recorded in C6D6 and DMSO-d6. The effect of change of solvents<br/>results appreciable change in the chemical shifts of various protons in the title compounds. 
<br/><br/><label>Subjects--Topical Terms: </label><br/>GENERAL CHEMISTRY