000			a
999			_c16141 _d16141
003			OSt
005			20220201150529.0
008			220201b xxu||||| |||| 00| 0 eng d
040			_aAIKTC-KRRC _cAIKTC-KRRC
100			_911679 _aUtsukihara, Takamitsu
245			_aProduction of chiral aromatic alcohol by acetophenone and 1-arylethanol derivatives using vegetables
250			_aVol.58(B), Jan.
260			_aNew Delhi _bCSIR _c2019
300			_a69-74p.
520			_aWe have studied the biotransformation of acetophenone derivatives (1a-1f) and 1-arylethanol derivatives (2a-2e, 2g, 2h) using various vegetables. It is found that the reduction of acetophenone derivatives (1a-1f) using carrot (Ducus carota) gives (S)-1-arylethanols with high enantioselectivity. On the other hand, biooxidation of 1-arylethanols (2a-2e, 2g, 2h) using potato (Solanum tuberosum) is oxidized to give (R)-1-arylethanols as major product with high stereoselectivity. Carrot (D. carota) is the best catalyst for this reduction and shows a good reaction yield and enatioselectivity. On the other hand, it is found that the racemic alcohols are converted into the corresponding (R)-alcohols with high ee using Japanese potato (S. tuberosum) as catalyst. The availability of the enzymatic system using various vegetables is convenient and an eco-friendly system.
650		0	_95009 _aGENERAL CHEMISTRY
700			_911877 _aHoriuchi, C. Akira
773	0		_dNew Delhi NISCAIR-CSIR 2005 _tIndian journal of chemistry (Section B)
856			_uhttp://nopr.niscair.res.in/bitstream/123456789/45707/1/IJCB%2058B%281%29%2069-74.pdf _yClick here
942			_2ddc _cAR