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999			_c19243 _d19243
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005			20230427142153.0
008			230427b xxu||||| |||| 00| 0 eng d
040			_aAIKTC-KRRC _cAIKTC-KRRC
100			_920583 _aMallik, Tapati
245			_aSolvation and Solvatochromism: An Overview
250			_aVol.61(5), May
260			_aNew Delhi _bCSIR _c2022
300			_a472-481p.
520			_aDifferent examples of solvatochromic shifts are shown and the theory that explain the non-specific general solvent effects are discussed here. The use of solvatochromic shifts for the determination of excited state dipole moment has been presented in detail in connection with a brief overview of different solvent polarity functions. The lack of proper theoretical expressions to explain the specific solvent effect stimulates to introduce the concept of “empirical measures of solvent polarity”, based on well known, convenient, solvent sensitive model processes. Various solvent sensitive polarity probes are discussed in this context. So far as quantitative estimation of various parameters responsible for the observed solvatochromic shifts are concerned, introduction of multiparameter approaches, its application in recent years has been carefully analyzed. The review also focuses some of the recent developments on the theoretical calculations of various solute-solvent interaction parameters based on quantum mechanical approaches. This issue solvation interaction by the use of mixed solvents has been discussed in detail, starting from the early development of the theories related to preferential solvation to the recent scenario, with a critical survey on the application of the concept of preferential solvation in the solubilization of drugs, polymers considering the emerging ‘green approach’ in recent years.
650		0	_95009 _aGENERAL CHEMISTRY
700			_920584 _aBanerjee, Debashis
773	0		_dNew Delhi NISCAIR-CSIR 2005 _x0019-5103 _tIndian journal of chemistry (Section B)
856			_uhttp://op.niscpr.res.in/index.php/IJC/article/view/63635 _yClick here
942			_2ddc _cAR