Experimental and Kinetic Modeling Study of Cyclohexane and Its Mono-alkylated Derivatives Combustion [electronic resource] /

By:

Wang, Zhandong [author.]

Contributor(s):

SpringerLink (Online service)

Language: ENG Series: Springer Theses, Recognizing Outstanding Ph.D. ResearchPublisher: Singapore : Springer Singapore : Imprint: Springer, 2018Edition: 1st ed. 2018Description: XIII, 216 p. 119 illus., 42 illus. in color. | Binding - Card Paper |Content type:

text

Media type:

computer

Carrier type:

online resource

ISBN:

9789811056932

Subject(s):

Additional physical formats: Printed edition:: No title; Printed edition:: No title; Printed edition:: No titleDDC classification:

621.4021 23

Online resources:

Click here to access eBook in Springer Nature platform. (Within Campus only.)

In: Springer Nature eBookSummary: This thesis investigates the combustion chemistry of cyclohexane, methylcyclohexane, and ethylcyclohexane on the basis of state-of-the-art synchrotron radiation photoionization mass spectrometry experiments, quantum chemistry calculations, and extensive kinetic modeling. It explores the initial decomposition mechanism and distribution of the intermediates, proposes a novel formation mechanism of aromatics, and develops a detailed kinetic model to predict the three cycloalkanes’ combustion properties under a wide range of conditions. Accordingly, the thesis provides an essential basis for studying much more complex cycloalkanes in transport fuels and has applications in engine and fuel design, as well as emission control.

List(s) this item appears in: Springer Nature eBooks

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This thesis investigates the combustion chemistry of cyclohexane, methylcyclohexane, and ethylcyclohexane on the basis of state-of-the-art synchrotron radiation photoionization mass spectrometry experiments, quantum chemistry calculations, and extensive kinetic modeling. It explores the initial decomposition mechanism and distribution of the intermediates, proposes a novel formation mechanism of aromatics, and develops a detailed kinetic model to predict the three cycloalkanes’ combustion properties under a wide range of conditions. Accordingly, the thesis provides an essential basis for studying much more complex cycloalkanes in transport fuels and has applications in engine and fuel design, as well as emission control.

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